Cu phen 2 oh 2 2+
WebOct 29, 2024 · The coordination compounds [Cu(phen) 2 (HL)]ClO 4 ·H 2 O. 2DMF (1) and [Cu(phen) 2 (HL) 2]·EtOH (2) were prepared by mixing the components Cu II : phen : H 2 L in a molar ratio of 1 : 2 : 1, where copper perchlorate or copper acetate salts were utilized. In the synthesis of compound 1, it was necessary to deprotonate the ligand H 2 L by adding … WebNov 12, 2024 · Compound 2 consists of polymeric Cu 2 (OH)(oda)(phen) 2 chains in which Cu 2 (OH)(phen) 2 dimers are linked by bridging oda ligands. The compounds were evaluated for in vitro anticancer efficacy and were found to exhibit significant activities against human-derived pancreatic and liver cancer cells.
Cu phen 2 oh 2 2+
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WebDec 3, 2013 · An unusual 4e – oxidation of Cl – into ClO 2 – occurred during the reaction between CuCl and phenanthroline (phen) in air to form a [Cu(phen) 2]ClO 2 complex, … WebA Cu(II) complex [Cu(bipy)(H2O)2(SO4)] n (bipy = 2,2'-bipyridine) was synthesized by hydrothermal method and characterized structurally by elemental analyses, single crystal X-ray diffraction ...
WebThe crystal structures of [Cu(phen) 2 (OH 2)][CF 3 SO 3] 2 1 and [Cu(phen) 2 (OH 2)][ClO 4] 2 2 (phen = 1,10-phenanthroline) have been determined by diffractometer data … WebDec 22, 2024 · The chiral Cu(II) complexes [Cu(phen)(L-Val)(OH 2)](NO 3)∙2H 2 O (Figure 19a) and [Cu(phen)(D-Val)(ONO 2)]∙3H 2 O (Figure 19b) of Arjmand et al. shows anticancer potency in the micromolar order on breast (MCF-7), pancreatic (BxPC3, AsPC1) and liver (Huh7) cancer cells. Notably, these compounds are able to target G-quadruplex DNA …
WebFeb 15, 2024 · In the growing field of single-molecule mechanochromism, the potential of transition metal complexes is yet to be examined. In this work, we have synthesized a … The flexibility of the [Cu(phen) 2]+ complexes has been observed in the … WebDec 5, 2015 · Reaction of yellow elemental sulfur (S 8) with green [Cu(phen) 2 OH 2](ClO 4) 2 (1) in methanol at room temperature in equimolar proportion yields a turquoise blue …
WebThe data obtained by potentiometric measurements were analysed using the LETAGROP least squares software. For the binary Cu(II)-1,10ʹ-Phenanthroline system the complexes [Cu(Phen)] 2+, Cu(OH) 2 (Phen) and [Cu 2 (OH) 2 (Phen) 2] 2+ were detected.
WebSep 1, 2012 · Cu(II) complexes with 1,10-orthophenanthroline (phen) show cytotoxic and antitumoral effects. To enhance and exploit these features, we studied complexes containing one or two phen units together with N,N′-substituted-imidazolidine-2-thione (L).We synthesized and structurally characterized the precursor molecule Cu(phen)(OH 2) 2 … swiss performance index sxegWebJun 14, 2024 · Different-metal different-ligand complexes [{Co(Phen)3}2{Co(Phen)(H2O)4}2][{Ge(μ-OH)(μ- Hedp)}6Cl2] (I), … swiss perfection llc syracuse inWebDec 22, 2024 · Structures of the [Cu(phen) 2 (CAn)](NO 3) 2 complexes. The introduction of an auxiliary carboxylate moiety allowed to increase the affinity towards ct-DNA while reducing that towards albumin. swiss performance chemicals usa incWebMar 15, 2024 · ABSTRACT The formation of the binary Cu(II)-1,10ʹ-Phenanthroline (Phen, L) in aqueous solution was studied by means of electromotive force measurements (EMF). In addition, the Cu(II)-2,2ʹ-Bipyridine (Bipy, L) and Cu(II)-1,10ʹ-Phenanthroline ternary complexes were studied using the low molecular weight blood serum ligands: lactate … swissperfusionWebApr 1, 2011 · Cu(I)-phenanthroline [Cu(phen) 2] + complexes have been shown to be useful building blocks in strategies for construction of supramolecular systems such as … swiss performance chemicals service agWebMar 1, 2000 · After 2 weeks, blue prismatic single crystals were obtained. An X-ray diffraction analysis revealed that the compound consists of one discrete [Cu(phen) 2 Cl] … swiss performance index spiWebCu(II) complexes with 1,10-orthophenanthroline (phen) show cytotoxic and antitumoral effects. To enhance and exploit these features, we studied complexes containing one or … swiss perfumes hamriyah free zone